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Magnetite-cobalt ferrite nanoparticles for kerosene-based magnetic fluids
OSCAR EDUARDO AYALA VALENZUELA
JOSE ANDRES MATUTES AQUINO
REBECA BETANCOURT GALINDO
LUIS ALFONSO GARCIA CERDA
Acceso Abierto
Sin Derechos Reservados
Cobalt
Due to the magnetic anisotropy introduced by the Co2+ ion in octahedral sites of cubic spinel ferrites, it is possible to tailor the magnetic properties by changing the cobalt content. Magnetic fluids with magnetite-cobalt ferrite nanoparticles given by the formula Co(x)Fe(3-x)O4 with x = 0, 0.2 and 0.4 were prepared. Kerosene and oleic acid were used as liquid carrier and surfactant, respectively. Spherical magnetic nanoparticles were obtained by coprecipitation from metal salts and ammonium hydroxide; afterwards the magnetic fluids were obtained by a peptization process. Powder properties were characterized by X-ray diffraction (XRD), nitrogen adsorption–desorption isotherma (BET), vibrating sample magnetometry (VSM) and fluids by transmission electron microscopy (TEM), thermogravimetric analyzer (TGA), VSM and the short-circuited transmission line technique.
2005
Artículo
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