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http://cimav.repositorioinstitucional.mx/jspui/handle/1004/1177| Functionalization of Polymers Hydroxyl-Terminated Using Oxoammonium Bromide Salt. Facile Synthetic Pathway Using Nitroxide Chemistry | |
| JOSE BONILLA CRUZ TANIA ERNESTINA LARA CENICEROS ENRIQUE SALDIVAR GUERRA | |
| Acceso Abierto | |
| Sin Derechos Reservados | |
| Polymers Hydroxyl-Terminated | |
| TEMPO bromide salt (Br-TEMPO) is used to functionalize polymers containing hydroxyl terminated groups whit nitroxide moieties. The functionalization reaction takes place in 24 h under mild conditions in solution. FT-IR and 1H-NMR analysis show that these polymers were for first time functionalized with nitroxide moieties using this synthetic pathway. A reaction mechanism is proposed in order to explain the findings, where we postulate the formation in situ of peroxidic bonds. This peroxidic bond was quantified by titration finding moderate functionalization levels (~50%). The results suggest that the oxoammonium salts are good candidates for the functionalization of polymers containing hydroxyl groups. | |
| 2008 | |
| Memoria de congreso | |
| Inglés | |
| OTRAS | |
| Versión revisada | |
| submittedVersion - Versión revisada | |
| Aparece en las colecciones: | Artículos de Congresos |
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| Fichero | Tamaño | Formato | |
|---|---|---|---|
| Macromex 2008.pdf | 153.66 kB | Adobe PDF | Visualizar/Abrir |